TY - JOUR
T1 - Biomass-derived Carbon–Silicon Composites (C@Si) as Anodes For Lithium-ion and Sodium-ion Batteries: A Promising Strategy Towards Long-term Cycling Stability: A Mini Review
AU - Reis, Glaydson Simoes dos
AU - Molaiyan, Palanivel
AU - Subramaniyam, Chandrasekar M
AU - García-Alvarado, Flaviano
AU - Paolella, Andrea
AU - Oliveira, Helinando Pequeno de
AU - Lassi, Ulla
PY - 2023/7
Y1 - 2023/7
N2 - The global need for high energy density and performing rechargeable batteries has led to the development of high-capacity silicon-based anode materials to meet the energy demands imposed to electrify plug-in vehicles to curtail carbon emissions by 2035. Unfortunately, the high theoretical capacity (4200 mA h g(-1)) of silicon by (de)alloy mechanism is limited by its severe volume changes (Delta V similar to 200% - 400%) during cycling for lithium-ion batteries (LIBs), while for sodium-ion batteries (NIBs) remain uncertain, and hence, compositing with carbons (C@Si) represent a promising strategy to enable the aforementioned practical application. The present review outlines the recent progress of biomass-derived Si-carbon composite (C@Si) anodes for LIBs and NIBs. In this perspective, we present different types of biomass precursors, silicon sources, and compositing strategies, and how these impact on the C@Si physicochemical properties and their electrochemical performance are discussed.
AB - The global need for high energy density and performing rechargeable batteries has led to the development of high-capacity silicon-based anode materials to meet the energy demands imposed to electrify plug-in vehicles to curtail carbon emissions by 2035. Unfortunately, the high theoretical capacity (4200 mA h g(-1)) of silicon by (de)alloy mechanism is limited by its severe volume changes (Delta V similar to 200% - 400%) during cycling for lithium-ion batteries (LIBs), while for sodium-ion batteries (NIBs) remain uncertain, and hence, compositing with carbons (C@Si) represent a promising strategy to enable the aforementioned practical application. The present review outlines the recent progress of biomass-derived Si-carbon composite (C@Si) anodes for LIBs and NIBs. In this perspective, we present different types of biomass precursors, silicon sources, and compositing strategies, and how these impact on the C@Si physicochemical properties and their electrochemical performance are discussed.
UR - http://dx.doi.org/10.1016/j.elecom.2023.107536
U2 - 10.1016/j.elecom.2023.107536
DO - 10.1016/j.elecom.2023.107536
M3 - Article
SN - 1388-2481
VL - 153
JO - Electrochemistry Communications
JF - Electrochemistry Communications
M1 - 107536
ER -