TY - JOUR
T1 - Hydrogen trapping and permeability in carbon fiber reinforced aluminum alloys
AU - Safyari, Mahdieh
AU - Rauscher, Alexander
AU - Ucsnik, Stephan
AU - Moshtaghi, Masoud
PY - 2024/1/1
Y1 - 2024/1/1
N2 - Carbon fibers and aluminum-based alloys are the most common choice for today's advanced hydrogen storage solutions due to their lightweight. They also combine excep-tional mechanical performance and resistance to most chemicals. However, carbon fibers alone are the primary cost driver for hydrogen storage systems and high-strength aluminum alloys suffer from hydrogen embrittlement. Therefore, alternative carbon fiber-reinforced aluminum alloys can be considered to optimize storage tank costs. But, the effect of adding of carbon fibers on hydrogen trapping in an aluminum-based matrix has not yet been understood. To elucidate this, in this study, the interaction between hydrogen and a carbon fiber-reinforced aluminum alloy was investigated by correlating nano/ microstructure characterization, hydrogen mapping techniques, and high-pressure hydrogen permeation tests. It is suggested that carbon fiber-reinforced aluminum alloy has three additional hydrogen trap sites compared to the reported traps for the aluminum alloy. The results showed that hydrogen trapping at these traps reduces the hydrogen permeability of composite material compared to a monolithic aluminum alloy.(c) 2023 The Author(s). Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC. This is an open access article under the CC BY license (http://creativecommons.org/ licenses/by/4.0/).
AB - Carbon fibers and aluminum-based alloys are the most common choice for today's advanced hydrogen storage solutions due to their lightweight. They also combine excep-tional mechanical performance and resistance to most chemicals. However, carbon fibers alone are the primary cost driver for hydrogen storage systems and high-strength aluminum alloys suffer from hydrogen embrittlement. Therefore, alternative carbon fiber-reinforced aluminum alloys can be considered to optimize storage tank costs. But, the effect of adding of carbon fibers on hydrogen trapping in an aluminum-based matrix has not yet been understood. To elucidate this, in this study, the interaction between hydrogen and a carbon fiber-reinforced aluminum alloy was investigated by correlating nano/ microstructure characterization, hydrogen mapping techniques, and high-pressure hydrogen permeation tests. It is suggested that carbon fiber-reinforced aluminum alloy has three additional hydrogen trap sites compared to the reported traps for the aluminum alloy. The results showed that hydrogen trapping at these traps reduces the hydrogen permeability of composite material compared to a monolithic aluminum alloy.(c) 2023 The Author(s). Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC. This is an open access article under the CC BY license (http://creativecommons.org/ licenses/by/4.0/).
KW - Carbon fiber reinforced composite
KW - Hydrogen permeability
KW - Hydrogen storage
KW - Hydrogen traps
KW - Multi-scale characterization
KW - Thermal desorption spectroscopy
UR - https://www.mendeley.com/catalogue/792b78a6-81d6-38e1-98d7-8b2e18f8e16a/
U2 - 10.1016/j.ijhydene.2023.09.206
DO - 10.1016/j.ijhydene.2023.09.206
M3 - Article
SN - 0360-3199
VL - 50
SP - 199
EP - 210
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
ER -