Diffusion Couples and High-Temperatures In-Situ Techniques: Tools for Establishing Phase Equilibria: The Ti-N, Nb-N and Ti-Nb-N Systems

Walter Lengauer; Birgit Wollein; Vincenzo Buscaglia; Riccardo Musenich; Marcel Bohn; Karine Lisak

Diffusion Couples and High-Temperatures In-Situ Techniques: Tools for Establishing Phase Equilibria: The Ti-N, Nb-N and Ti-Nb-N Systems

Walter Lengauer
, Birgit Wollein
, Vincenzo Buscaglia
, Riccardo Musenich
, Marcel Bohn
, Karine Lisak

TU Wien
Instituto Nazionale di Fiscia Nucleare in Genoa

Research output: Contribution to journal › Article › peer-review

Abstract

Following a review on the Ti-N and Nb-N systems the phase reactions in the Nb-N system are discussed. Insight into these systems was possible because of the use of in-situ investigation techniques such as DSC and HTXRD as well as diffusion couples, which partly represent an in-situ tool, too. Phase reactions in the Ti-Nb-N system were investigated by (Ti, Nb)N/Nb2/N diffusion couples and by nitridation. Metallography, EPMA and AES were employed for characterisation. The Nb2N phase dissolves a substantial amount of Ti. At 1800°C (Ti, Nb)N with 75 and 63% Ti atoms on the metal sublattice can demix into -Ti0.92Nb0.08N and -Ti0.60Nb0.40N.

Original language	German
Pages (from-to)	591-602
Number of pages	12
Journal	Advances of Sciences and Technology
Publication status	Published - 2000

Research Field

Not defined

Cite this

@article{fdc81cdc19fb428ea5f681730d06af43,

title = "Diffusion Couples and High-Temperatures In-Situ Techniques: Tools for Establishing Phase Equilibria: The Ti-N, Nb-N and Ti-Nb-N Systems",

abstract = "Following a review on the Ti-N and Nb-N systems the phase reactions in the Nb-N system are discussed. Insight into these systems was possible because of the use of in-situ investigation techniques such as DSC and HTXRD as well as diffusion couples, which partly represent an in-situ tool, too. Phase reactions in the Ti-Nb-N system were investigated by (Ti, Nb)N/Nb2/N diffusion couples and by nitridation. Metallography, EPMA and AES were employed for characterisation. The Nb2N phase dissolves a substantial amount of Ti. At 1800°C (Ti, Nb)N with 75 and 63\% Ti atoms on the metal sublattice can demix into -Ti0.92Nb0.08N and -Ti0.60Nb0.40N.",

author = "Walter Lengauer and Birgit Wollein and Vincenzo Buscaglia and Riccardo Musenich and Marcel Bohn and Karine Lisak",

year = "2000",

language = "Deutsch",

pages = "591--602",

}

TY - JOUR

T1 - Diffusion Couples and High-Temperatures In-Situ Techniques: Tools for Establishing Phase Equilibria: The Ti-N, Nb-N and Ti-Nb-N Systems

AU - Lengauer, Walter

AU - Wollein, Birgit

AU - Buscaglia, Vincenzo

AU - Musenich, Riccardo

AU - Bohn, Marcel

AU - Lisak, Karine

PY - 2000

Y1 - 2000

N2 - Following a review on the Ti-N and Nb-N systems the phase reactions in the Nb-N system are discussed. Insight into these systems was possible because of the use of in-situ investigation techniques such as DSC and HTXRD as well as diffusion couples, which partly represent an in-situ tool, too. Phase reactions in the Ti-Nb-N system were investigated by (Ti, Nb)N/Nb2/N diffusion couples and by nitridation. Metallography, EPMA and AES were employed for characterisation. The Nb2N phase dissolves a substantial amount of Ti. At 1800°C (Ti, Nb)N with 75 and 63% Ti atoms on the metal sublattice can demix into -Ti0.92Nb0.08N and -Ti0.60Nb0.40N.

AB - Following a review on the Ti-N and Nb-N systems the phase reactions in the Nb-N system are discussed. Insight into these systems was possible because of the use of in-situ investigation techniques such as DSC and HTXRD as well as diffusion couples, which partly represent an in-situ tool, too. Phase reactions in the Ti-Nb-N system were investigated by (Ti, Nb)N/Nb2/N diffusion couples and by nitridation. Metallography, EPMA and AES were employed for characterisation. The Nb2N phase dissolves a substantial amount of Ti. At 1800°C (Ti, Nb)N with 75 and 63% Ti atoms on the metal sublattice can demix into -Ti0.92Nb0.08N and -Ti0.60Nb0.40N.

M3 - Artikel

SP - 591

EP - 602

JO - Advances of Sciences and Technology

JF - Advances of Sciences and Technology

ER -